Some Representative Publications
 

1. V. P. Boyarskiy, K. V. Luzyanin, V. Yu. Kukushkin, Palladium-(acyclic diaminocarbene) Species as Alternative to Palladium-(nitrogen heterocyclic carbenes) in Cross-coupling Catalysis, in Advances in Organometallic Chemistry: The Silver/Gold Jubilee ICOMC Celebratory Book, Ed. A. J. P. Pombeiro, Wiley, 2013, Chapter 11, pp. 145–156. DOI: 10.1002/9781118742952.ch11

2. D. S. Bolotin, N. A. Bokach, M. Haukka, V. Yu. Kukushkin, Platinum(IV)-mediated nitrile–amidoxime coupling reactions: insights into the mechanism for the generation of 1,2,4-oxadiazoles, ChemPlusChem, 77 (2012) 31–40. DOI: 10.1002/cplu.201100047

3. A. S. Kritchenkov, N. A. Bokach, M. L. Kuznetsov, F. M. Dolgushin, T. Q. Tung, A. P. Molchanov, V. Yu. Kukushkin, Facile and reversible 1,3-dipolar cycloaddition of aryl ketonitrones to PtII-bound nitriles: synthetic, structural, and theoretical studies, Organometallics, 31 (2012) 687–699. DOI: 10.1021/om201026n

4. A. L. Mindich, N. A. Bokach, F. M. Dolgushin, M. Haukka, L. A. Lisitsyn, A. P. Zhdanov, K. Yu. Zhizhin, S. A. Miltsov, N. T. Kuznetsov, V. Yu. Kukushkin, 1,3-Dipolar cycloaddition of nitrones to nitriles bound to closo-decaborate clusters: a novel reactivity mode for the borylated CN group, Organometallics, 31 (2012) 1716–1724. DOI: 10.1021/om200993f

5. R. S. Chay, K. V. Luzyanin, V. Yu. Kukushkin, M. F. C. Guedes da Silva, A. J. L. Pombeiro, Novel palladium-aminocarbene species derived from metal-mediated coupling of isonitriles and 1,3-diiminoisoindoline: synthesis and the catalytic application in Suzuki–Miyaura cross-coupling, Organometallics, 31 (2012) 2379–2387. DOI: 10.1021/om300020j

6. P. V. Gushchin, M. L. Kuznetsov, Q. Wang, A. A. Karasik, M. Haukka, G. L. Starova, V. Yu. Kukushkin, Lasagna-type arrays with halide–nitromethane cluster filling. The first recognition of the Hal–•••HCH2NO2 (Hal = Cl, Br, I) hydrogen bonding, Dalton Trans., 41 (2012) 6922–6931. DOI: 10.1039/C2DT12394K 7. D. S. Bolotin, N. A. Bokach, M. Haukka, V. Yu. Kukushkin, Amidoximes provide facile platinum(II)-mediated oxime–nitrile coupling, Inorg. Chem., 51 (2012) 5950–5964. DOI: 10.1021/ic3006019

8. V. P. Boyarskiy, K. V. Luzyanin, V. Yu. Kukushkin, Acyclic diaminocarbenes (ADCs) as a promising alternative to N-heterocyclic carbenes (NHCs) in transition metal catalyzed organic transformations, Coord. Chem. Rev., 256 (2012) 2029–2056. DOI: 10.1016/j.ccr.2012.04.022

9. Yu. Yu. Scaffidi-Domianello, A. A. Legin, M. A. Jakupec, A. Roller, V. Yu. Kukushkin, M. Galanski, B. K. Keppler, Novel oximato-bridged platinum(II) di- and trimer(s): synthetic, structural, and in vitro anticancer activity studies, Inorg. Chem., 51 (2012), 7153–7163. DOI: 10.1021/ic300148e

10. A. N. Chernyshev, N. A. Bokach, P. V. Gushchin, M. Haukka, V. Yu. Kukushkin, Reactions of platinum(IV)-bound nitriles with the isomeric nitroanilines: addition vs. substitution, Dalton Trans., 41 (2012) 12857–12864. DOI: 10.1039/c2dt30986f

11. A. S. Kritchenkov, N. A. Bokach, G. L. Starova, V. Yu. Kukushkin, A Palladium(II)-center activates nitrile ligands toward 1,3-dipolar cycloaddition of nitrones substantially more than the corresponding platinum(II)-center, Inorg. Chem., 51 (2012) 11971–11979. DOI: 10.1021/ic301866y

12. A. L. Mindich, N. A. Bokach, M. L. Kuznetsov, M. Haukka, A. P. Zhdanov, K. Yu. Zhizhin, S. A. Miltsov, N. T. Kuznetsov, V. Yu. Kukushkin, Coupling of azomethine ylides with nitrilium derivatives of closo-decaborate clusters: synthetic and theoretical study, ChemPlusChem, 77 (2012) 1075–1086. DOI: 10.1002/cplu.201200257

13. A. S. Kritchenkov, K. V. Luzyanin, N. A. Bokach, M. L. Kuznetsov, G. L. Starova, V. Yu. Kukushkin, Selective nucleophilic oxygenation of palladium-bound isocyanide ligands: route to imino complexes that serve as efficient catalysts for copper-/phosphine-free Sonogashira reaction, Organometallics, 32 (2013) 1979–1987. DOI: 10.1021/om4000665

14. P. V. Gushchin, M. L. Kuznetsov, M. Haukka, V. Yu. Kukushkin, Recognition of a novel type X=N-Hal•••Hal’ (X = Ñ, S, P; Hal = F, Cl, Br, I) halogen bonding, J. Phys. Chem., A, 117 (2013) 2827–2834. DOI: 10.1021/jp3112149

15. D. S. Bolotin, N. A. Bokach, M. Haukka, V. Yu. Kukushkin, Amidrazone complexes from a cascade platinum(II)-mediated reaction between amidoximes and dialkylcyanamides, Inorg. Chem., 52 (2013) 6378–6389. DOI: 10.1021/ic4000878

16. N. A. Bokach, V. Yu. Kukushkin, Coordination chemistry of dialkylcyanamides: binding properties, synthesis of metal complexes, and ligand reactivity, Coord. Chem. Rev., 257 (2013) 2293–2316. DOI: 10.1016/j.ccr.2013.03.002

17. M. A. Kinzhalov, V. P. Boyarskiy, K. V. Luzyanin, F. M. Dolgushin, V. Yu. Kukushkin, Metal-mediated coupling of a coordinated isocyanide and indazoles, Dalton Trans., 42 (2013) 10394–10397. DOI: 10.1039/c3dt51335a

18. T. B. Anisimova, N. A. Bokach, F. M. Dolgushin, V. Yu. Kukushkin, Dialkylcyanamides are more reactive substrates toward metal-mediated nucleophilic addition than alkylcyanides, Dalton Trans., 42 (2013) 12460–12467. DOI: 10.1039/c3dt51137e

19. M. A. Kinzhalov, K. V. Luzyanin, V. P. Boyarskiy, M. Haukka, V. Yu. Kukushkin, ADC-Based palladium catalysts for aqueous Suzuki–Miyaura cross-coupling exhibit greater activity than the most advantageous catalytic systems, Organometallics, 32 (2013) 5212–5223. DOI: 10.1021/om4007592

20. A. L. Mindich, N. A. Bokach, M. L. Kuznetsov, G. L. Starova, A. P. Zhdanov, K. Yu. Zhizhin, S. A. Miltsov, N. T. Kuznetsov, V. Yu. Kukushkin, Borylated tetrazoles from ñycloaddition of azide anions to nitrilium derivatives of closo-decaborate clusters, Organometallics, 32 (2013) 6576–6586. DOI: 10.1021/om400892x

21. B. G. M. Rocha, E. A. Valishina, R. S. Chay, M. F. C. Guedes da Silva, T. M. Buslaeva, A. J. L. Pombeiro, V. Yu. Kukushkin, K. V. Luzyanin, ADC-metal complexes as effective catalysts for hydrosilylation of alkynes, J. Catal., 309 (2014) 79–86. DOI: 10.1016/j.jcat.2013.09.003

22. A. S. Kritchenkov, N. A. Bokach, M. Haukka, V. Yu. Kukushkin, Unexpectedly efficient activation of push-pull nitriles by a PtII center toward dipolar cycloaddition of Z-nitrones, Dalton Trans., 40 (2011) 4175–4182. DOI: 10.1039/c0dt01689f

23. A. G. Tskhovrebov, K. V. Luzyanin, M. L. Kuznetsov, V. N. Sorokoumov, I. A. Balova, M. Haukka, V. Yu. Kukushkin, Substituent R-dependent regioselectivity switch in nucleophilic addition of N-phenylbenzamidine to PdII- and PtII-complexed isonitrile RNC giving aminocarbene-like species, Organometallics, 30 (2011) 863–874. DOI: 10.1021/om101041g

24. N. A. Bokach, I. A. Balova, M. Haukka, V. Yu. Kukushkin, Highly stereoselective 1,3-dipolar cycloaddition of nitrones to (nitrile)2PtII species furnishing diastereomerically pure 2,3-dihydro-1,2,4-oxadiazole ligands, Organometallics, 30 (2011) 595–602. DOI: 10.1021/om100957b

25. P. V. Gushchin, G. L. Starova, M. Haukka, M. L. Kuznetsov, I. L. Eremenko, V. Yu. Kukushkin, Chloride–chloroform clusters exhibiting weak hydrogen and halogen bondings are fully characterized in the solid state by X-ray diffraction, Crystal Growth & Design, 10 (2010) 4839–4846. DOI: 10.1021/cg1007507

26. T. A. Anisimova, N. A. Bokach, K. V. Luzyanin, M. Haukka, V. Yu. Kukushkin, Push-pull nitrile ligands exhibit specific hydration patterns, Dalton Trans., 39 (2010) 10790–10798. DOI: 10.1039/c0dt00711k

27. M. L. Kuznetsov, V. Yu. Kukushkin, A. J. L. Pombeiro, Comparative theoretical study of 1,3-dipolar cycloadditions of allyl-anion type dipoles to free and Pt-bound nitriles, J. Org. Chem., 75 (2010) 1474–1490. DOI: 10.1021/jo902415d

28. N. A. Bokach, N. P. Konovalova, Y. Wang, Yu. E. Moskalenko, A. V. Gribanov, V. Yu. Kukushkin, One-end nucleophilic addition of di- and triamines to PtIV coordinated nitriles as an entry to (amidine)PtIV complexes bearing pendant NH2-groups, Dalton Trans., 2010, 4619–4623. DOI: 10.1039/c001103g

29. Yu. Scaffidi-Domianello, K. Meelich, M. A. Jakupec, V. B. Arion, V. Yu. Kukushkin, M. Galanski, B. K. Keppler, Novel cis- and trans-configured bis(oxime)platinum(II) complexes – synthesis, characterization, and cytotoxic activity, Inorg. Chem., 49 (2010) 5669–5678. DOI: 10.1021/ic100584b

30. K. V. Luzyanin, A. G. Tskhovrebov, M. C. Maia, M. F. C. Guedes da Silva, V. Yu. Kukushkin, A. J. L. Pombeiro, Novel metal-mediated (M = Pt, Pd) coupling between isonitriles and benzophenone hydrazone as a route to aminocarbene complexes exhibiting high catalytic activity (M = Pd) in the Suzuki–Miyaura reaction, Organometallics, 28 (2009) 6559–6566. DOI: 10.1021/om900682v

31. A. G. Tskhovrebov, N. A. Bokach, M. Haukka, V. Yu. Kukushkin, Different routes for amination of platinum(II)-bound cyanoguanidine, Inorg. Chem., 48 (2009) 8678–8688. DOI: 10.1021/ic900263e

32. N. A. Bokach, M. L. Kuznetsov, M. Haukka, V. I. Ovcharenko, E. V. Tretyakov, V. Yu. Kukushkin, PtII-Complexed tetrahydroimidazo[1,2-b][1,2,4]oxadiazoles derived from metal-mediated 1,3-dipolar cycloaddition. Novel type of heterocycles, which do not exist without the metal center, Organometallics, 28 (2009) 1406–1413. DOI: 10.1021/om800963d

33. P. V. Gushchin, M. L. Kuznetsov, M. Haukka, M.-J. Wang, A. V. Gribanov, V. Yu. Kukushkin, A novel reactivity mode for metal-activated dialkylcyanamide species: Addition of N,N'-diphenylguanidine to a cis-(R2NCN)2PtII center giving an eight-membered chelated platinaguanidine, Inorg. Chem., 48 (2009) 2583–2592. DOI: 10.1021/ic802109d

34. K. V. Luzyanin, A. G. Tshovrebov, M. F. C. Guedes da Silva, M. Haukka, A. J. L. Pombeiro, V. Yu. Kukushkin, Metal-mediated [2 + 3] cycloaddition of nitrones to palladium-bound isonitriles, Chem. Eur. J., 15 (2009) 5969–5978. DOI: 10.1002/chem.200802623

35. K. V. Luzyanin, A. J. L. Pombeiro, M. Haukka, V. Yu. Kukushkin, Coupling between 3-iminoisoindolin-1-ones and complexed isonitriles as a metal-mediated route to a novel type of palladium and platinum iminocarbene species, Organometallics, 27 (2008) 5379–5389. DOI: 10.1021/om800517c

36. M. R. Tyan, N. A. Bokach, M.-J. Wang, M. Haukka, M. L. Kuznetsov, V. Yu. Kukushkin, Facile cyanamide–ammonia coupling mediated by cis- and trans-[PtIIL2] centers and giving metal-bound guanidines, Dalton Trans., 2008, 5178–5188. DOI: 10.1039/b806862c

37. M. N. Kopylovich, K. V. Luzyanin, M. Haukka, A. J. L. Pombeiro, V. Yu. Kukushkin, Copper-mediated imine–nitrile coupling leading to unsymmetric 1,3,5-triazapentadienato complexes containing the incorporated iminoisoindolin-1-one moiety, Dalton Trans., 2008, 5220–5224. DOI: 10.1039/b805243c

38. P. V. Gushchin, M. R. Tyan, N. A. Bokach, M. D. Revenco, M. Haukka, M.-J. Wang, C.-H. Lai, P.-T. Chou, V. Yu. Kukushkin, Novel tailoring reaction for two adjacent coordinated nitriles giving 1,3,5-triazapentadiene Pt-complexes, Inorg. Chem., 47 (2008) 11487–11500. DOI: 10.1021/ic702483w

39. K. V. Luzyanin, P. V. Gushchin, A. J. L. Pombeiro, M. Haukka, V. I. Ovcharenko, V. Yu. Kukushkin, Oxidation of Pt-bound bis-hydroxylamine as a novel route to unexplored dinitrosoalkane ligated species, Inorg. Chem., 47 (2008) 6919–6930. DOI: 10.1021/ic800481a

40. P. V. Gushchin, K. V. Luzyanin, M. N. Kopylovich, M. Haukka, A. J. L. Pombeiro, V. Yu. Kukushkin, NiII-Mediated coupling between iminoisoindolinones and nitriles leading to unsymmetrical 1,3,5-triazapentadienato complexes, Inorg. Chem., 47 (2008) 3088–3094. DOI: 10.1021/ic702131k

41. M. L. Kuznetsov, V. Yu. Kukushkin, A. J. L. Pombeiro, Reactivity of Pt- and Pd-bound nitriles towards nitrile oxides and nitrones: substitution versus cycloaddition, Dalton Trans., 2008, 1312–1322. DOI: 10.1039/b713425h

42. K. V. Luzyanin, V. Yu. Kukushkin, M. N. Kopylovich, A. A. Nazarov, M. Galanski, M. Haukka, A. J. L. Pombeiro, A novel and expedient route to 3-iminoisoindolin-1-ones via reaction of phthalonitriles with N,N-diethylhydroxylamine, Adv. Synth. Catal., 350 (2008) 135–142. DOI: 10.1002/adsc.200700261

43. A. V. Makarycheva-Mikhailova, J. A. Golenetskaya, N. A. Bokach, I. A. Balova, M. Haukka, V. Yu. Kukushkin, PtII-Mediated 1,3-dipolar cycloaddition of oxazoline N-oxides to nitriles as a key step to dihydrooxazolo-1,2,4-oxadiazoles, Inorg. Chem., 46 (2007) 8323–8331. DOI: 10.1021/ic701133b

44. Y. Yu. Scaffidi-Domianello, A. A. Nazarov, M. Haukka, M. Galanski, B. K. Keppler, J. Schneider, P. Du, R. Eisenberg, V. Yu. Kukushkin, First example of the solid state thermal cyclometalation of ligated benzophenone imine giving novel luminescent platinum(II) species, Inorg. Chem., 46 (2007) 4469–4482. DOI: 10.1021/ic062414k

45. M. L. Kuznetsov, A. A. Nazarov, L. V. Kozlova, V. Yu. Kukushkin, Theoretical study of chemo-, regio-, and stereoselectivity in 1,3-dipolar cycloadditions of nitrones and nitrile oxides to free and Pt-bound bifunctional alkenyl- and alkynyl nitriles, J. Org. Chem., 72 (2007) 4475–4485. DOI: 10.1021/jo0703597

46. P. V. Gushchin, N. A. Bokach, K. V. Luzyanin, A. A. Nazarov, M. Haukka, V. Yu. Kukushkin, PtII-mediated nitrile-tetramethylguanidine coupling as a key step for a novel synthesis of 1,6-dihydro-1,3,5-triazines, Inorg. Chem., 46 (2007), 1684–1693. DOI: 10.1021/ic061884b

47. M. N. Kopylovich, M. Haukka, A. M. Kirillov, V. Yu. Kukushkin, A. J. L. Pombeiro, Unsymmetrical imidoylamidine NiII complexes derived from a novel oxime-mediated single-pot reaction of nitriles, Chem. Eur. J., 13 (2007) 786–791. DOI: 10.1002/chem.200600765

48. S. Zorbas-Seifried, M. A. Jakupec, N. V. Kukushkin, M. Groessl, C. Hartinger, O. Semenova, H. Zorbas, V. Yu. Kukushkin, B. K. Keppler, Reversion of structure-activity relationships of antitumor platinum complexes by acetoxime but not hydroxylamine ligands, Molecular Pharmacology, 71 (2007) 357–365. DOI: 10.1124/mol.106.030726

49. G. H. Sarova, N. A. Bokach, A. A. Fedorov, M. N. Berberan-Santos, V. Yu. Kukushkin, M. Haukka, J. J. R. Fraústo da Silva, A. J. L. Pombeiro, A new family of luminescent compounds: platinum(II) imidoylamidinates exhibiting pH-dependent room temperature luminescence, Dalton Trans., 2006, 3798–3805. DOI: 10.1039/B602083F

50. M. L. Kuznetsov, V. Yu. Kukushkin, Theoretical study of reactant activation in 1,3-dipolar cycloadditions of cyclic nitrones to free and Pt-bound nitriles, J. Org. Chem., 71 (2006) 582–592. DOI: 10.1021/jo051958l

51. K. V. Luzyanin, V. Yu. Kukushkin, M. L. Kuznetsov, A. D. Ryabov, M. Galanski, M. Haukka, E. V. Tretyakov, V. I. Ovcharenko, M. N. Kopylovich, A. J. L. Pombeiro, Kinetic and thermodynamic aspects of the regioselective addition of bifunctional hydroxylaminooxime-type HO-nucleophiles to Pt-complexed nitriles, Inorg. Chem., 45 (2006) 2296–2306. DOI: 10.1021/ic051909r

52. A. V. Khripun, V. Yu. Kukushkin, S. I. Selivanov, M. Haukka, A. J. L. Pombeiro, Unusual reaction between (nitrile)Pt complexes and pyrazoles: substitution proceeds via metal-mediated nitrile–pyrazole coupling followed by elimination of the nitrile, Inorg. Chem., 45 (2006) 5073–5083. DOI: 10.1021/ic0602300

53. K. V. Luzyanin, V. Yu. Kukushkin, A. D. Ryabov, M. Haukka, A. J. L. Pombeiro, Kinetic and mechanistic study of the Pt(II) versus Pt(IV) effect in the platinum-mediated nitrile–hydroxylamine coupling, Inorg. Chem., 44 (2005) 2944–2953. DOI: 10.1021/ic048388c

54. N. A. Bokach, T. V. Kuznetsova, S. A. Simanova, M. Haukka, A. J. L. Pombeiro, V. Yu. Kukushkin, Nitrile–amidine coupling at Pt(IV) and Pt(II) centers. An easy entry to imidoylamidine complexes, Inorg. Chem., 44 (2005) 5152–5160. DOI: 10.1021/ic050037q

55. N. A. Bokach, V. Yu. Kukushkin, P. F. Kelly, M. Haukka, A. J. L. Pombeiro, The first examples of metal-mediated addition of a phosphorus imine to nitriles; the preparation and X-ray crystal structures of [PtCl4{NH=C(Et)N=PPh3}2] and [PtCl2(EtCN){NH=C(Et)N=PPh3}], Dalton Trans., 2005, 1354–1356. DOI: 10.1039/B502970H

56. D. A. Garnovskii, A. J. L. Pombeiro, M. Haukka, P. Sobota, V. Yu. Kukushkin, Regioselective HON-addition of bifunctional hydrazone oximes to Pt(IV)-bound nitriles, Dalton Trans., 2004, 1097–1103. DOI: 10.1039/B402105C

57. K. V. Luzyanin, V. Yu. Kukushkin, M. Haukka, J. J. R. Fraústo da Silva, A. J. L. Pombeiro, The Metalla-Pinner reaction between Pt(IV)-bound nitriles and alkylated oxamic and oximic forms of hydroxamic acids, Dalton Trans., 2004, 2727–2731. DOI: 10.1039/B406600F

58. E. Reisner, V. B. Arion, M. F. C. Guedes da Silva, R. Lichtenecker, A. Eichinger, B. K. Keppler, V. Yu. Kukushkin, A. J. L. Pombeiro, Tuning of redox potentials for the design of ruthenium anticancer drugs. An electrochemical study of [trans-RuCl4L(DMSO)]- and [trans-RuCl4L2]- complexes, where L = imidazole, 1,2,4-triazole, indazole, Inorg. Chem., 43 (2004) 7083–7093. DOI: 10.1021/ic049479c

59. M. N. Kopylovich, V. Yu. Kukushkin, M. Haukka, K. V. Luzyanin, A. J. L. Pombeiro, A novel efficient synthesis of phthalocyanines based on an unprecedented double-addition of oximes to phthalonitriles (a communication), J. Amer. Chem. Soc., 126 (2004) 15040–15041. DOI: 10.1021/ja046759i

List of Publications
for the Past Years


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          2011

          2010

          2009

          2008

          2007

          2006

          2005

          2004

          2003

          2002

          2001

          2000

          1999

          1998

 

© 2002—2014, Professor V.Yu. Kukushkin Group. © 2002—2014, Dr. Konstantin Luzyanin, webdesign.