Metal-Mediated and
Metal-Catalyzed Reactions of Isocyanides

by V.P. Boyarskiy, N.A. Bokach, K.V. Luzyanin,
and V.Yu. Kukushkin

Chemical Reviews, 2015, 115, 2698–2779.
DOI: 10.1021/cr500380d

The essential goals of this Review are
(i) to attempt to systematize and explain
many diverse data on metal-mediated and
metal-catalyzed conversions of isocyanides
and to give a general outlook of reaction
routes, mechanisms, and driving forces; and
(ii) to underline the potential of metal-
involved conversions of CNR in synthetic
organometallic and organic chemistry and
draw attention to the emerging targets.

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